Title: Manipulating Small Water Droplets on A Photo-switchable Mat of Fluorinated Linear Liquid Crystal Polymers

Author: Xiao Zhang, Lang Qin, Yuyun Liu, Jia Wei, Yanlei Yu*

Journal: Giant, 2020, 2, 100019

Abstract:

Manipulating small water droplets on an intelligent surface with tunable superhydrophobic adhesion has attracted considerable interests because of potential applications ranging from no-loss transfer to surface chemistry but remains challenging. Herein, we present a strategy to manipulate the small water droplet on a photo-switchable mat, which is fabricated by a fluorinated linear liquid crystal polymer via electrospinning. The electrospun mat with hierarchical microstructures exhibits fast and reversible superhydrophobic adhesion change, and still remains the superhydrophobicity after pinning and removing of the water droplets for several times. Diverse erasable and rewritable arrays on the vertically placed mat are formed by pinning the small water droplets to any high adhesive position after localized light irradiation. Moreover, after evaporation of the water droplets containing aggregation-induced emission materials, the mat exhibits bright fluorescence upon faint UV irradiation to indicate the trace with the same pattern as the original droplets. Such photo-switchable superhydrophobic mats would provide an open tunable surface for microdroplets manipulation.


论文链接:https://www.sciencedirect.com/science/article/pii/S2666542520300229?via%3Dihub

PDF下载Manipulating Small Water Droplets on A Photo-switchable Mat of Fluorinated Linear Liquid Crystal Polymers.pdf


本文通过静电纺丝技术将氟化线性液晶聚合物(LLCP)制备成具有分级微结构的光控超疏水垫。由于表面纳米纤维产生的分层结构,电纺垫具有超疏水性,并且因为偶氮苯的可逆顺反光致异构化引起的表面自由能的改变,电纺垫可在几秒钟内发生超疏水粘附状态的变化。同时,利用氟化来降低表面能,实现了对微米级水滴(≤ 4 μL)的操控。此外,通过将溶有水溶性AIE的微米级水滴预先粘附在“LC”阵列上,在水分蒸发后,残留的AIE化合物会在紫外光激发下发出明亮的荧光,进一步展示了其在防伪技术中的应用。